Hello Bryce, welcome!
You mentioned "throttle bodies", but I assume this is a US bike with two carburetors, correct?
Don't use starter fluid. The delicate diaphragms in the carbs can be damaged from that, and they're expensive to replace.
I'd start with a compression test. The problem could be valves that aren't sealing, maybe because of rust, or maybe because they've never been adjusted and are no longer seating.
I'll defer to @
ducatiman for the question about the decel valve.